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When connected to your new (or existing) controller or transmitter, it will provide the auto temp comp that you need. The temperature element is usually incorporated into the matching cable assembly (electrode holder). When it is time to replace the pH electrode cartridge, the ATC element remains behind, sealed in the cable assembly, waiting for a fresh pH electrode.
To determine if Automatic Temperature Compensation is required for your installation, see the table below.
The
need for automatic compensation depends on three variables:
- The changes in temperature
- The pH value being measured
- The desired measurement accuracy.
As shown in the following
table, the pH error due to temperature is a function of both the
temperature and the pH value being measured. At a pH of about 7,
there is no error due to temperature. At a temperature of
25 degrees C, there is no error.
The more the temperature
changes from the ambient calibration temperature and the more
the pH departs from 7, the greater is the pH error. The GRAY colored
temperature/pH combinations have zero error due to temperature
effects and the light blue colored combinations have less than
0.1 pH unit error.
Whether or not automatic
temperature compensation is needed is determined by the application's
accuracy requirement. For example, a waste water application with
pH varying between 5 and 9 and temperature varying between 5 and
45 degrees C has a maximum error of 0.12 pH unit. If the needed
accuracy is 0.5 pH unit, then automatic compensation is not needed.
In a process liquid where
pH varies from 3 to 11 and the temperature varies from 25 to 75
degrees C, the error is 0.6 pH unit and automatic compensation probably
is required.
If you decide, after reviewing the
table, that need Automatic Temperature Compensation in your pH electrode
system, select the appropriate cable assembly (for submersion) or
flow cell-cable (for in-line) or ATC Insertion assembly.
pH vs. Temperature Error Chart
| |
pH 2 |
pH 3 |
pH 4 |
pH 5 |
pH 6 |
pH 7 |
pH 8 |
pH 9 |
pH 10 |
pH 11 |
pH 12 |
| 5° |
.30 |
.24 |
.18 |
.12 |
.06 |
0 |
.06 |
.12 |
.18 |
.24 |
.30 |
| 15° |
.15 |
.12 |
.09 |
.06 |
.03 |
0 |
.03 |
.06 |
.09 |
.12 |
.15 |
| 25° |
0 |
0 |
0 |
0 |
0 |
0 |
0 |
0 |
0 |
0 |
0 |
| 35° |
.15 |
.12 |
.09 |
.06 |
.03 |
0 |
.03 |
.06 |
.09 |
.12 |
.15 |
| 45° |
.30 |
.24 |
.18 |
.12 |
.06 |
0 |
.06 |
.12 |
.18 |
.24 |
.30 |
| 55° |
.45 |
.36 |
.27 |
.18 |
.09 |
0 |
.09 |
.18 |
.27 |
.36 |
.45 |
| 65° |
.60 |
.48 |
.36 |
.24 |
.12 |
0 |
.12 |
.24 |
.36 |
.48 |
.60 |
| 75° |
.75 |
.60 |
.45 |
.30 |
.15 |
0 |
.15 |
.30 |
.45 |
.60 |
.75 |
| 85° |
.90 |
.72 |
.54 |
.36 |
.18 |
0 |
.18 |
.36 |
.54 |
.72 |
.90 |
Note:
Values in light blue are less than .1 error and may not require
temperature compensation. Values in
gray are temperature and pH in which there is no error in pH from
temperature. |